Line tension and reduction of apparent contact angle associated with electric double layers
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چکیده
منابع مشابه
Three-phase contact line and line tension of electrolyte solutions in contact with charged substrates.
The three-phase contact line formed by the intersection of a liquid-vapor interface of an electrolyte solution with a charged planar substrate is studied in terms of classical density functional theory applied to a lattice model. The influence of the substrate charge density and of the ionic strength of the solution on the intrinsic structure of the three-phase contact line and on the correspon...
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Hydration interactions: aqueous solvent effects in electric double layers
A model for ionic solutions with an attractive short-range pair interaction between the ions is presented. The short-range interaction is accounted for by adding a quadratic nonlocal term to the Poisson-Boltzmann free energy. The model is used to study solvent effects in a planar electric double layer. The counterion density is found to increase near the charged surface, as compared with the Po...
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ژورنال
عنوان ژورنال: Physics of Fluids
سال: 2014
ISSN: 1070-6631,1089-7666
DOI: 10.1063/1.4892621